Safety

Lithium-ion batteries can rupture, ignite, or explode when exposed to high temperature environments, for example in an area that is prone to prolonged direct sunlight. Short-circuiting a Li-ion battery can cause it to ignite or explode, and as such, any attempt to open or modify a Li-ion battery's casing or circuitry is dangerous. Li-ion batteries contain safety devices that protect the cells inside from abuse, and, if damaged, can cause the battery to ignite or explode.
Contaminants inside the cells can defeat these safety devices. For example, the mid-2006 recall of approximately 10 million Sony batteries used in Dell, Sony, Apple, Lenovo/IBM, Panasonic, Toshiba, Hitachi, Fujitsu and Sharp laptops was stated to be as a consequence of internal contamination with metal particles. Under some circumstances, these can pierce the separator, causing the cell to short, rapidly converting all of the energy in the cell to heat resulting in an exothermic oxidizing reaction, increasing the temperature to a few hundred degrees Celsius in a fraction of a second.[41] This causes the neighboring cells to heat up, causing a chain thermal reaction. The mid-2006 Sony laptop battery recall was not the first of its kind, however it was the largest to date.
During the past decade there have been numerous recalls of lithium-ion batteries in cellular phones and laptops owing to overheating problems. In October 2004, Kyocera Wireless recalled approximately 1 million batteries used in cellular phones, due to counterfeit batteries produced in Kyocera's name. In December 2006, Dell recalled approximately 22,000 batteries from the U.S. market. March 2007, Lenovo recalled approximately 205,000 9-cell lithium-ion batteries due to an explosion risk. In August 2007, Nokia recalled over 46 million lithium-ion batteries, warning that some of them might overheat and possibly explode.[44] There was an incident in the Philippines involving a Nokia N91, which uses
the BL-5C battery. It is possible to replace the lithium cobalt oxide cathode material in li-ion batteries with lithiated metal phosphate cathodes that are not as sensitive to temperature, and so are less prone to explode. This also extends their shelf life. However, currently these 'safer' li-ion batteries are mainly destined for electric cars and other large-capacity battery applications, where the safety issues are more critical. Unfortunately, a problem with these 'safer' li-ion batteries is that lithiated metal phosphate batteries only about 75 percent as much energy.Another option is to use manganese oxide or ironphosphate cathode.